Physical and Chemical Properties of Crystalline Systems

Unlike crystallization from melting and freezing, heat transfer is not the decisive process in cystallization from solution because the properties of the crystalline product depend primarily on supersaturation generated by cooling, evaporation, drowning out, or a reaction. The quality components of the product (i.e., its crystal size distribution, its median crystal size, its purity, and its crystal shape) are strongly inﬂuenced by (a) the geometry and type of the crystallizer, (b) the operating conditions, and (c) the properties of the liquid and solid phases.

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